Bis[4-(2-isopropyl-2H-tetrazol-5-yl)phenyl]dimethylsilane
نویسندگان
چکیده
The title compound, C(22)H(28)N(8)Si, has crystallographic 2 symmetry with the Si atom located on a twofold rotation axis. The tetra-zole ring is oriented at a dihedral angle of 5.32 (18)° with respect to the benzene ring. A C-H⋯π inter-action occurs between adjacent mol-ecules in the crystal structure.
منابع مشابه
Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ2 N 4,N 5}zinc(II)
The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydro-thermal reaction of ZnBr(2) with 2-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octa-hedral environment with two planar trans-related N,N'-chelating 2-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]acetic acid ligands in the equatorial plane and two water mol-ecules ...
متن کاملcatena-Poly[[di-μ-bromido-dicopper(I)]bis[μ-η2,σ1-4-(2-allyl-2H-tetrazol-5-yl)pyridine]]
The title compound, [CuBr(C(9)H(9)N(5))](n), prepared by the solvothermal treatment of CuBr with 4-(2-allyl-2H-tetra-zol-5-yl)pyridine, is a new homometallic Cu(I)-olefin coordination polymer in which dinuclear Cu(2)Br(2) units are linked by the organic olefin ligand 4-(2-allyl-2H-tetra-zol-5-yl)pyridine, which acts as a bidentate ligand connecting two neighbouring Cu(2)Br(2) units through the ...
متن کاملtrans-Diaquabis{1,3-bis[5-(2-pyridyl)-2H-tetrazol-2-yl]propane}zinc(II) bis(perchlorate)
The Zn(II) ion in the title compound, [Zn(C(15)H(14)N(10))(H(2)O)(2)](ClO(4))(2), lies on a centre of symmetry. The distorted N(4)O(2) octa-hedral coordination environment around the Zn atom is composed of two 1,3-bis-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]propane ligands (L1) and two water mol-ecules, coordinated in trans positions. The ligand acts as a typical bidentate chelating ligand through on...
متن کامل2-{4-[5-(3-Pyridyl)-2H-tetrazol-2-ylmethyl]phenyl}benzonitrile
In the title compound, C(20)H(14)N(6), there are two mol-ecules with similar conformations in the asymmetric unit. The pyridine and tetra-zole rings are nearly coplanar; they are twisted from each other by dihedral angles of only 8.7 (2) and 7.4 (2)°. The nearer benzene ring makes dihedral angles of 69.9 (2) and 88.5 (2)° with the tetra-zole ring in the two mol-ecules.
متن کاملTetrakis{4-[(2H-tetrazol-5-yl)methyl]morpholin-4-ium} dodecatungstosilicate hexahydrate
The crystal structure of the title compound, (C(6)H(12)N(5)O)(4)[W(12)(SiO(4))O(36)]·6H(2)O, consists of an α-Keggin-type [W(12)(SiO(4))O(36)](4-) polyoxidoanion, four [(2H-tetra-zol-5-yl)meth-yl]morpholinium cations and six uncoordinated water mol-ecules. In the cations, the morpholine rings display chair conformations. Extensive N-H⋯O, N-H⋯N, O-H⋯O and O-H⋯N hydrogen bonds are present in the ...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011